Discussion:
Unbound states of the hydrogen atom
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Michael Cole
2020-04-26 09:25:29 UTC
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Hi all. Does anyone know where to find a good elegant mathematical
treatment of the quantum hydrogen atom? The bound states are, of
course, treated in every textbook, but they usually don't address the
unbound states. I tried to tackle it myself as an exercise, but I am
having trouble finding the right normalization of the continuous
spectrum of unbound energy states. Is there a good reference for this?
Hendrik van Hees
2020-04-26 22:06:28 UTC
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A very nice treatment of the full hydrogen problem is in

J. J. Sakurai, Modern Quantum Mechanics, Addison Wesley

using the standard wave-mechanical techniques.
Post by Michael Cole
Hi all. Does anyone know where to find a good elegant mathematical
treatment of the quantum hydrogen atom? The bound states are, of
course, treated in every textbook, but they usually don't address the
unbound states. I tried to tackle it myself as an exercise, but I am
having trouble finding the right normalization of the continuous
spectrum of unbound energy states. Is there a good reference for this?
--
Hendrik van Hees
Goethe University (Institute for Theoretical Physics)
D-60438 Frankfurt am Main
http://fias.uni-frankfurt.de/~hees/
Jos Bergervoet
2020-04-26 22:06:42 UTC
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Post by Michael Cole
Hi all. Does anyone know where to find a good elegant mathematical
treatment of the quantum hydrogen atom? The bound states are, of
course, treated in every textbook, but they usually don't address the
unbound states. I tried to tackle it myself as an exercise, but I am
having trouble finding the right normalization of the continuous
spectrum of unbound energy states. Is there a good reference for this?
These unbound states of course do not have a finite norm for the
integrated wave function squared, but presumably you mean the
normalization convention for the "Coulomb wave functions".

The treatment in A&S handles that on page 538. See:
http://people.math.sfu.ca/~cbm/aands/subj.htm
"Coulomb wave functions ..... 509, 537"
--
Jos
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